Use Roll Over Rig Info button (RORI) in SMR Helpers to transfer the metadata from one container to another.
You will find details and video demonstration here.
If you use the FreeStyle Rigging tool after breaking apart the head, this will give it a different ID than the one of the container, while if you roll it over with RORI you will maintain rig integrity.
You can check element IDs when you load the rig in Smart Magnet Rig panel, then hover over the nodes. The ID will be displayed in the status bar at the bottom of the panel.
If you already have your structures in place, you can use any symbol instance to transfer SMR info from the outer wrapper to the head angles inside:
Just create a box on the head container layer, convert it to a symbol and use RORI to write the SMR info into it.
Then cut it and paste it inside the container where your head angles are. Select it and use RORI to write that same SMR info into the head angles. Then delete the temp instance.
Now when you break apart, the different head angles will be part of the same rig.